Fuel options for Solid Oxide Fuel Cells: A Thermodynamic Analysis


Authors
S. Douvartzides, F.A. Coutelieris, A. Demin, P. Tsiakaras
Publication Year
2003
Journal Name
AIChE J.
Volume
49
Pages
248-257
Citations
53
Research Area
Modelling of Fuel Cells

Abstract:
The eligibility of natural gas (methane), methanol, ethanol, and gasoline as fuels for the generation of electrical power in solid oxide fuel cells (SOFCs) is discussed in terms of efficiency. Each raw fuel was assumed to be processed in a steam reformer to provide a hydrogen-rich gas mixture to the SOFC feedstream. An SOFC system, consisting of an electrochemical section and a reformer, was analyzed thermodynamically assuming initial steamrfuel feed ratios at conditions where carbon deposition is thermodynamically impossible, at atmospheric total pressure, and in the temperature range of 800 to 1,200 K. Results were obtained in terms of both electromoti®e force (emf) output and efficiency. Methane seems to be the most appropriate fuel option, with an SOFC system efficiency close to 96%. Furthermore, ethanol and methanol were ®ery promising alternati®e options (94% and 91%, respecti®ely), while gasoline (83%) utilization requires special reforming conditions.
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