Fuel options for Solid Oxide Fuel Cells: A Thermodynamic Analysis
Authors |
S. Douvartzides, F.A. Coutelieris, A. Demin, P. Tsiakaras |
Publication Year |
2003 |
Journal Name |
AIChE J. |
Volume |
49 |
Pages |
248-257 |
Citations |
53 |
Research Area |
Modelling of Fuel Cells |
Abstract:
The eligibility of natural gas (methane), methanol, ethanol, and gasoline as fuels for
the generation of electrical power in solid oxide fuel cells (SOFCs) is discussed in terms
of efficiency. Each raw fuel was assumed to be processed in a steam reformer to provide
a hydrogen-rich gas mixture to the SOFC feedstream. An SOFC system, consisting of
an electrochemical section and a reformer, was analyzed thermodynamically assuming
initial steamrfuel feed ratios at conditions where carbon deposition is thermodynamically
impossible, at atmospheric total pressure, and in the temperature range of 800 to 1,200 K. Results were obtained in terms of both electromoti®e force (emf) output and efficiency. Methane seems to be the most appropriate fuel option, with an SOFC system efficiency close to 96%. Furthermore, ethanol and methanol were ®ery promising alternati®e options (94% and 91%, respecti®ely), while gasoline (83%) utilization requires special reforming conditions.