The effect of the porosity on the adsorption rate in granular porous media
Authors |
F.A. Coutelieris, M. Kainourgiakis, A. Stubos |
Publication Year |
2002 |
Journal Name |
Stud. Surf. Sci. Catalysis |
Volume |
144 |
Pages |
753-760 |
Abstract:
The Sherwood number representing the mass transfer coefficient for transport from a
moving fluid to a swarm of spherical particles is calculated in the range of high porosities.
The mass transport problem is solved both analytically and numerically under the assumption
of instantaneous adsorption upon the liquid-solid interface. The velocity components within
the liquid phase are obtained either by using the analytical formulations of the sphere-in-cell
model or by solving numerically the creeping flow problem in a stochastically constructed
packing of spheres. It is found that the agreement between numerical and analytical data is in
general reasonably good for the porosity range considered. Limitations of both the numerical
and analytical approaches are identified. Numerical predictions are deteriorating rapidly for
extremely high porosities (above 0.95). On the other hand, the accuracy of analytically
obtained Sherwood values becomes weaker as the porosity decreases because the fundamental assumptions of the analytical model are not satisfied in this case.